内容

目次

1. What is organic chemistry?; 2. Organic structures; 3. Determiningorganic structures; 4. Structure of molecules; 5. Organic reactions; 6.Nucleophilic addition to the carbonyl group; 7. Delocalization andconjugation; 8. Acidity, basicity, and pKa; 9. Using organometallic reagentsto make C-C bonds; 10. Conjugate addition; 11. Proton nuclear magneticresonance; 12. Nucleophilic substitution at the carbonyl (C=O) group; 13.Equilibria, rates, and mechanisms: summary of mechanistic principles; 14.Nucleophilic substitution at C=O with loss of carbonyl oxygen; 15. Review ofspectroscopic methods; 16. Stereochemistry; 17. Nucleophilic substitution atsaturated carbon; 18. Conformational analysis; 19. Elimination reactions; 20.Electrophilic addition to alkenes; 21. Formation and reactions of enols andenolates; 22. Electrophilic aromatic substitution; 23. Electrophilic alkenes;24. Chemoselectivity: selective reactions and protection; 25. Synthesis inaction; 26. Alkylation of enolates; 27. Reactions of enolates with aldehydesand ketones: the aldol reaction; 28. Acylation at carbon; 29. Conjugateaddition of enolates; 30. Retrosynthetic analysis; 31. Controlling thegeometry of double bonds; 32. Determination of stereochemistry byspectroscopic; 33. Stereoselective reactions of cyclic compounds; 34.Diastereoselectivity; 35. Pericyclic reactions 1: cycloadditions; 36.Pericyclic reactions 2: sigmatropic and electrocyclic reactions; 37.Rearrangements; 38. Fragmentation; 39. Radical reactions; 40. Synthesis andreactions of carbenes; 41. Determining reaction mechanisms; 42. Saturatedheterocycles and stereoelectronics; 43. Aromatic heterocycles 1: structuresand reactions; 44. Aromatic heterocycles 2: synthesis; 45. Asymmetricsynthesis; 46. Organo-main-group chemistry I: sulfur; 47. Organo-main-groupchemistry II: boron, silicon, and tin; 48. Organometallic chemistry; 49. Thechemistry of life; 50. Mechanisms in biological chemistry; 51. Naturalproducts; 52. Polymerization; 53. Organic chemistry today; INDEX