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目次

Foreword Preface to the Fourth Edition 1 INTRODUCTION 1.1 Historical Perspective 1.2 Types of Ion Chromatography 1.3 The Ion Chromatographic System 1.4 Advantages of Ion Chromatography 1.5 Selection of Separation and Detection Systems 2 THEORY OF CHROMATOGRAPHY 2.1 Chromatographic Terms 2.2 Parameters for Assessing the Quality of a Separation 2.3 Column Efficiency 2.4 The Concept of Theoretical Plates (van Deemter Theory) 2.5 Van Deemter Curves in Ion Chromatography 3 ANION–EXCHANGE CHROMATOGRAPHY (HPIC) 3.1 General Remarks 3.2 The Ion–Exchange Process 3.3 Thermodynamic Aspects 3.4 Stationary Phases 3.5 Eluents for Anion–Exchange Chromatography 3.6 Suppressor Systems in Anion–Exchange Chromatography 3.7 Anion–Exchange Chromatography of Inorganic Anions 3.8 Anion–Exchange Chromatography of Organic Anions 3.9 Gradient Elution Techniques in Anion–Exchange Chromatography of Inorganic and Organic Anions 3.10 Carbohydrates 3.11 Amino Acids 3.12 Anion–Exchange Chromatography of Proteins 3.13 Nucleic Acids 4 CATION–EXCHANGE CHROMATOGRAPHY (HPIC) 4.1 Stationary Phases 4.2 Eluents in Cation–Exchange Chromatography 4.3 Suppressor Systems in Cation–Exchange Chromatography 4.4 Cation–Exchange Chromatography of Alkali Metals, Alkaline–Earth Metals, and Amines 4.5 Transition Metal Analysis 4.6 Analysis of Polyamines 4.7 Gradient Techniques in Cation–Exchange Chromatography of Inorganic and Organic Cations 4.8 Cation–Exchange Chromatography of Proteins 5 ION–EXCLUSION CHROMATOGRAPHY (HPICE) 5.1 The Ion–Exclusion Process 5.2 Stationary Phases 5.3 Eluents for Ion–Exclusion Chromatography 5.4 Suppressor Systems in Ion–Exclusion Chromatography 5.5 Analysis of Inorganic Acids 5.6 Analysis of Organic Acids 5.7 HPICE/HPIC–Coupling 5.8 Analysis of Alcohols and Aldehydes 5.9 Amino Acids Analysis 5.10 Size–Exclusion Chromatography of Proteins 6 ION–PAIR CHROMATOGRAPHY (MPIC) 6.1 Survey of Existing Retention Models 6.2 Suppressor Systems in Ion–Pair Chromatography 6.3 Experimental Parameters that Affect Retention 6.4 Analysis of Surface–Inactive Ions 6.5 Analysis of Surface–Active Ions 6.6 Applications of the Ion–Suppression Technique 6.7 Applications of Ion Chromatography on Mixed–Mode Stationary Phases 7 HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHY (HILIC) 7.1 Separation Mechanism in Hydrophilic Interaction Liquid Chromatography 7.2 Stationary Phases for HILIC 7.3 Factors Affecting Retention in HILIC 7.4 Applications 8 DETECTION METHODS IN ION CHROMATOGRAPHY 8.1 Electrochemical Detection Methods 8.2 Spectrometric Detection Methods 8.3 Aerosol–Based Detection Methods 8.4 Other Detection Methods 8.5 Hyphenated Techniques 9 QUANTITATIVE ANALYSIS 9.1 General 9.2 Analytical Chemical Information Parameters 9.3 Determination of Peak Areas 9.4 Statistical Quantities 9.5 Calibration of an Analytical Method (Basic Calibration) 9.6 Detection Criteria, Limit of Detection, Limit of Determination 9.7 The System of Quality Control Cards 10 APPLICATIONS 10.1 Ion Chromatography in Environmental Analysis 10.2 Ion Chromatography in Power Plant Chemistry 10.3 Ion Chromatography in the Semiconductor Industry 10.4 Ion Chromatography in the Electroplating Industry 10.5 Ion Chromatography in the Detergent and Household Product Industry 10.6 Ion Chromatography in the Food and Beverage Industry 10.7 Ion Chromatography in the Pharmaceutical Industry 10.8 Ion Chromatography in Clinical Chemistry 10.9 Oligosaccharide Analysis of Membrane–Coupled Glycoproteins 10.10 Chemical and Petrochemical Applications 10.11 Other Applications 10.12 Sample Preparation and Matrix Problems 10.13 Concluding Remarks